Probabilities of rare events in product kernel aggregation: exact formula and phase diagram
by
P1A
Dipartimento di Fisica e Astronomia - Edificio Ricci-Curbastro (ex-Paolotti)
We present an exact method for calculating the large deviation
function describing rare fluctuations in the number of particles for
product-kernel aggregation. Starting from the master equation, we
derive an exact integral representation for the probability $P(M,N,t)$
of observing $N$ particles at time $t$ starting from $M$ monomers for
any finite $M, N, t$. From this, we obtain an exact expression for
the exponential moment $\langle p^N\rangle$ for integer $p$. Employing
a replica conjecture---numerically validated by finite-$M$
scaling---we extend this result to real $p \geq 0$. The convex
envelope of the large deviation function, obtained via a
Legendre-Fenchel transform of the exponential moment, shows singular
behavior. The singular structure allows us to construct the full phase
diagram of product-kernel aggregation, which contains a tricritical
point, separating continuous and discontinuous transitions. We also
compute the asymptotic form of the LDF for small $N/M$.